Metal organic framework anchored onto biowaste mediated carbon material (rGO) for remediation of chromium (VI) by the photocatalytic process.

Groundwater contaminated with hexavalent chromium Cr(VI) causes serious health concerns for the ecosystem. In this study, a hybrid amino functionalized MOF@rGO nanocatalyst was produced by utilization of a biowaste mediated carbon material (reduced graphene oxide; rGO) and its surface was modified by in situ synthesis of a nanocrystalline, mixed ligand octahedral MOF containing iron metal and NH2 functional groups and the prepared composite was investigated for Cr (VI) removal. The photocatalytic degradation of Cr(VI) in aqueous solutions was carried out under UV irradiation. Using a batch mode system, the effect of numerous control variables was examined, and the process design and optimization were carried out by response surface methodology (RSM). The photocatalyst, NH2-MIL(53)-Fe@rGO, was intended to be a stable and highly effective nanocatalyst throughout the recycling tests. XRD, SEM, EDS, FTIR examinations were exploited to discover more about surface carbon embedded with MOF. 2 g/L of NH2-MIL-53(Fe)/rGO was utilized in degrading 200 mg/L of Cr(VI) in just 100 min, implying the selective efficacy of such a MOF-rGO nanocatalyst. Moreover, the Eg determinations well agreed with the predicted range of 2.7 eV, confirming its possibility to be exploited underneath visible light, via the Tauc plot. Thus, MOF anchored onto biowaste derived rGO photo-catalyst was successfully implemented in chromium degradation.

Deep insights into kinetics, optimization and thermodynamic estimates of methylene blue adsorption from aqueous solution onto coffee husk (Coffee arabica) activated carbon.

In the current study, an attempt was made to synthesize coffee husk (CH) activated carbon by chemical modification approach (sulphuric acid-activated CH (SACH) activated carbon) and was used as a valuable and economical sorbent for plausible remediation of Methylene blue (MB) dye. Batch mode trials were carried out by carefully varying the batch experimental variables: SACH activated carbon (SACH AC) dosage, pH, initial dye concentration, temperature, and contact time. The optimum equilibrium time for adsorption by SACH activated carbon was obtained as 60 min, and the maximum adsorption took place at 30 °C. Morphological and elemental composition, crystallinity behaviour, functional groups, and thermal stability were examined using SEM with EDX, XRD, FTIR, BET, TGA, and DTA and these tests showed successful production of activated carbon. The outcomes showed that chemical activation enhanced the number of pores and roughness which possibly maximized the adsorptive potential of coffee husk. The Box-Benken design (BBD) was used to optimize the MB dye adsorption studies and 99.48% MB dye removed at SACH AC dosage of 4.83 g/L at 30 °C for 60 min and pH 8.12, and the maximum adsorption was yielded for sulphuric acid-activated coffee husk carbon carbon with 88.1 mg/g maximum MB adsorption capacity. Langmuir- Freundlich model deliberately provided a better fit to the equilibrium data. The SACH AC-MB dye system kinetics showed a high goodness-of-fit with pseudo second order model, compared to other studied models. Change in Gibbs's free energy (ΔGo) of the system indicated spontaneity whereas low entropy value (ΔSo) suggested that the removal of MB dye on the SACH activated carbon was an enthalpy-driven process. The exothermic nature of the sorption cycle was affirmed by the negative enthalpy value (ΔHo). The adsorptive-desorptive studies reveal that SACH AC could be restored with the maximum adsorption efficiency being conserved after the fifth cycles. Overall, the outcomes revealed that sulphuric acid-activated coffee husk activated carbon (SACH AC) can be used as prompt alternative for low-cost sorbent for treating dye-laden synthetic wastewaters.

Bio-waste mediated synthesis of zirconium nanoparticle fuel: Energy management strategy for performance evaluation in a diesel engine.

The impact of biosynthesized zirconium nanoparticles originated from biological waste, blended in diesel fuel processed through bio-refining strategy and its combustion, emissions, and overall diesel engine performance towards safety has been examined. Different weight fractions of zirconia nanoparticles were combined with crude diesel at 10, 20, and 30 mg/L values. According to the engine tests, Zirconia (20 nm) added to pure diesel at a concentration of 30 parts per million incremented thermal efficiencies by 4.9% compared to regular diesel fuel. The average reduction in specific fuel consumption for clean diesel fuel when the engine was operating at full power was 2.9%, 3.9%, and 4.9%. Diesel smoke, hydrocarbon, CO, and NOx emissions were reduced by 13%, 20%, 25%, and 29%, respectively, when nano additives were used at a concentration of 30 ppm.Nanoparticles enhance fuel stability, overcome detonation difficulties, and avoid fouling spark plugs. The pressure within cylinder, the temperature, and the rate at which heat is released was improved when alumina nanoparticles were appended to diesel fuel. However, both the length of the combustion and further delay in ignition were cut down. The ideal concentration of zirconia nanoparticles for improving combustion, efficiency, and emissions along with safety attainment in an internal combustion engine is recorded at 30 ppm.

Adsorptive removal of acid blue dye 113 using three agricultural waste biomasses: The possibility of valorization by activation and carbonization - A comparative analysis.

The presence of various organic and inorganic contaminants in wastewater leads to serious health effects on humans and ecosystems. Industrial effluents have been considered as noticeable sources of contaminating water streams. These effluents directly liberate the pollutants such as dye molecules and heavy metal ions into the environment. In the present study, three biowaste materials (groundnut shell powder, coconut coir powder and activated corn leaf carbon) were utilized and compared for the removal of acid blue dye 113 from aqueous solutions. The characterization study of newly prepared sorbent material (H3PO4-activated corn leaf carbon) and the other utilized sorbents was carried out by Scanning Electron Microscope (SEM) and Fourier Transform Infrared Spectrophotometer (FTIR), along with Energy Dispersive X-Ray (EDX) Analysis. The influence of experimental conditions such as pH, initial dye concentration, temperature, contact time, and sorbent dosage on the removal efficiency of the dye were appraised. The adsorption isotherm and kinetic result of acid blue dye 113 adsorption onto the sorbents best obeyed from Sips and pseudo-second-order kinetic model. Overall, the outcomes confirmed that the newly synthesized sorbent material (carbonized H3PO4-activated corn leaf) has superior adsorption capacity, rapid adsorption, and higher suitability for the removal of toxic dyes from the contaminated waters.

Progress and Prospective of the Industrial Development and Applications of Eco-Friendly Colorants: An Insight into Environmental Impact and Sustainability Issues.

Color is the prime feature directly associated with the consumer's attraction and choice of their food. The flavor, safety, and nutritional value of any food product are directly associated with the food color. Natural and synthetic colorants (dyes and pigments) have diversified applications in various sectors such as food, feed, pharmaceutical, textiles, cosmetics, and others. Concerning the food industry, different types of natural and synthetic colorants are available in the market. Synthetic food colorants have gained popularity as they are highly stable and cheaply available. Consumers worldwide prefer delightful foodstuffs but are more concerned about the safety of the food. After its disposal, the colloidal particles present in the synthetic colorants do not allow sunlight to penetrate aquatic bodies. This causes a foul smell and turbidity formation and gives a bad appearance. Furthermore, different studies carried out previously have presented the toxicological, carcinogenic effects, hypersensitivity reactions, and behavioral changes linked to the usage of synthetic colorants. Natural food colorings, however, have nutraceutical qualities that are valuable to human health such as curcumin extracted from turmeric and beta-carotene extracted from carrots. In addition, natural colorants have beneficial properties such as excellent antioxidant properties, antimutagenic, anti-inflammatory, antineoplastic, and antiarthritic effects. This review summarizes the sources of natural and synthetic colorants, their production rate, demand, extraction, and characterization of food colorants, their industrial applications, environmental impact, challenges in the sustainable utilization of natural colorants, and their prospects.

Agricultural waste biomass for sustainable bioenergy production: Feedstock, characterization and pre-treatment methodologies.

The worldwide trend in energy production is moving toward circular economy systems and sustainable availability of sources. Some advanced methods support the economic development of energy production by the utilization of waste biomass, while limiting ecological effects. The use of agro waste biomass is viewed as a major alternative energy source that expressively lowers greenhouse gas emissions. Agricultural residues produced as wastes after each step of agricultural production are used as sustainable biomass assets for bioenergy production. Nevertheless, agro waste biomass needs to go through a few cyclic changes, among which biomass pre-treatment contributes to the removal of lignin and has a significant role in the efficiency and yield of bioenergy production. As a result of rapid innovation in the utilization of agro waste for biomass-derived bioenergy, a comprehensive overview of the thrilling highlights and necessary advancements, in addition to a detailed analysis of feedstock, characterization, bioconversion, and contemporary pre-treatment procedures, appear to be vital. To this end, the current status in the generation of bioenergy from agro biomass through various pre-treatment procedures was examined in this study, along with presenting relevant challenges and a perspective for future investigations.

Evaluation of methyl orange adsorption potential of green synthesized chitosan-silver nanocomposite (CS-AgNC) and its notable biocompatibility on freshwater Tilapia (Oreochromis nitoticus).

Nanomaterials mainly nanocomposites possess unique physical and chemical properties which makes them superior and indispensable. Though much research has been focused on the properties and application of nanocomposites, the eco-toxicity assessment is one among top priority, which aims to protect the population of concerned biological component and their ecosystem. With this objective, the present study has undertaken an initiation to evaluate the efficacy of chitosan-silver nanocomposite for methyl orange adsorption property (CS-AgNC) and also assessed the toxicity impact on growth parameters of freshwater Tilapia. Batch in vitro studies showed that all the tested dosages of the nanocomposite were effectively adsorbing maximum concentration of methyl orange. The synthesized nanocomposite was administrated to the tested fishes followed by the determination of various growth, nutritional parameters, gene expression of enzymatic antioxidants and liver, and intestinal tissues histology. Obtained results indicated that nanocomposite treatment was not projected as a toxic impact on all the tested growth, and nutritional parameters. Histology study showed that the exposure of Tilapia to nanocomposite has not shown any detrimental effect on antioxidants gene expression and liver, intestinal tissue architecture. Hence, all these findings indicated that chitosan-silver nanocomposite prepared in our present system was found to be biocompatible which suggested the possible utilization and release of the nanocomposite into the divergent ecosystem without affecting non-target organisms (NTO).

Effect of Ca2+ ions on naphthalene adsorption/desorption onto calcium oxide nanoparticle: Adsorption isotherm, kinetics and regeneration studies.

The adsorptive nature of calcium oxide nanoparticles in aqueous sample of naphthalene in presence of Ca2+ ions was estimated. Enhanced efficiency of calcium oxide regeneration (90%) with the aid of calcium chloride in the solution concentration of 0.002-0.1 M was depicted. The less degree of toxic naphthalene desorption merged with SEM, FTIR and XRD characterization data portrays the importance of naphthalene adsorption onto calcium oxide using calcium chloride for regeneration. Batch adsorption studies were performed to evaluate the operating parameters such as pH, naphthalene concentration, contact time and impact of Ca2+ on naphthalene study. The adsorption isotherm of naphthalene on calcium oxide nanoparticle was described by Langmuir, Freundlich, Temkin and Dubinin Radushkevich and theoretical maximum monolayer adsorption capacity was found to be 63.81 mg/g at 303 K. The adsorption kinetic best fitted with pseudo second order kinetic model. The positive influence of making the addition of Ca2+ ions into naphthalene solution for its rapid adsorption was elucidated which is leaded by a probable increase in sorption capacity for naphthalene molecules at lower concentrations. The stable nature of crystallinity of calcium oxide and a less degree of naphthalene molecules leaching during consecutive cycles of adsorptive process and nanoparticle regeneration was also scrutinized.

Feasibility of magnetic nano adsorbent impregnated with activated carbon from animal bone waste: Application for the chromium (VI) removal.

Chromium is the heavy metal which existing in the effluents cause extensive discomfort to the environmental components. Bone waste is widely generated in food processing industries and restaurants. It is now used by switching into activated carbon. By co-precipitation procedure, the activated carbon is coated with a nano adsorbent. The Fe3O4-BAC adsorbent potential was established in this study via several batch tests. The adsorbing adverts had super magnetic behavior, and the magnetization value was 22 emu/g. The SEM imaging of the Fe3O4-BAC shows an improved morphology of 100-446 nm, and the nanoparticles were monodispersed. The present investigation also delves into the study of system parameters on the removal of metal ions. Optimal adsorption has been found at the acidic pH at the contact time of 60min for the adsorbent amount of 5 g/L. Maximum capacity of adsorption by nano adsorbent was 27.86 mg/g. Thermodynamic and isotherm tests have established the process viability. In addition, the kinetic studies establish the inclination of the studied Fe3O4-BAC towards pseudo-first order models. Hence, Fe3O4-BAC could be potential adsorbent to remove chromium from an aqueous solution.

Molecular intervention of colon cancer and inflammation manifestation by tannin capped biocompatible controlled sized gold nanoparticles from Terminalia bellirica: A green strategy for pharmacological drug formulation based on nanotechnology principles.

Among the diverse nanomaterials, gold nanoparticles (AuNps) are utilised for various therapeutic application due to the distinct physical, chemical properties and biocompatibility. Synthesis of gold nanoparticles using plants is the promising route. This method is low cost, eco-friendly and higher biological activities. In this present study, Gold nanoparticles were synthesised from fruit extract of Terminalia bellirica fruit extract. Their anticancer and anti-inflammatory activity was evaluated against colorectal cancer cell line (HT29) and TNBS-induced zebrafish model. Highly stable tannin capped gold nanoparticles were synthesised from fruit extract broth of Terminalia bellirica rapidly. Structural and functional properties of the synthesised nanoparticles were studied by Fourier transform infrared spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM) equipped with energy-dispersive atomic X-ray spectroscopy (EDAX) and X-ray diffraction (XRD). All the characterisation studies reveal highly stable, crystalline, phytochemicals, mainly tannin doped, spherical, 28 nm controlled sized gold nanoparticles. The molecular mechanism of anticancer activity was studied by determining cancer markers' expression, which was studied using quantitative real-time polymerase chain reaction (qPCR). Antioxidative enzymes' status and apoptosis changes were also investigated. Synthesised nanoparticles brought a drastic reduction of all the tested cancer markers' expression. Notable changes in antioxidative enzymes' status and a good sign of apoptosis were observed in nanoparticles' treatment. The anti-inflammatory activity was studied against TNBS-induced zebrafish model, which was confirmed by determining inflammatory markers' expression TNF-α, iNOS (induced Nitric Oxide Synthase) and histopathological examination. Nanoparticles' treatment recorded a drastic reduction of inflammatory markers' expression. No marked sign of inflammation was also observed in histopathological analysis of the nanoparticles' treatment group. The present study suggests the possible utilisation of T. bellirica-mediated gold nanoparticles as an effective therapeutic agent against a prolonged inflammatory disease that progressively develops into cancer.

Acenaphthene adsorption onto ultrasonic assisted fatty acid mediated porous activated carbon-characterization, isotherm and kinetic studies.

Adsorbents originated from biological materials play a vital role in the remediation of diverse toxic pollutants due to their high efficacy, low cost and being environmentally friendly. The present study focusses on the palm shell activated carbon obtained from agricultural waste precursor (palm shell) with the aid of oleic acid activation along with ultrasonic assistance and its effective utilization for acenaphthene adsorption from aqueous and real effluent. The synthesized Ultrasonic assisted palm shell activated carbon (UAC) possessed high surface area of 506.84 m2/g and distinct porous structure as depicted by SEM analysis. The outcomes of zero discharge analyses and acenaphthene adsorption results vouchsafed that, using oleic acid as an effective catalyst, is explicitly advantageous to combine with ultrasonic assistance to fabricate a highly efficient adsorbent for acenaphthene removal from aqueous solution. The UAC obtained at the selected parameters levels, such as temperature of 45 °C and ultrasonic time of 40 min, has the adsorption capacity of 52.745 mg/g. Sips isotherm model computed from the experimental data gave the best fit among the examined isotherm models. To complete the study of adsorption properties of UAC towards acenaphthene, kinetic modeling and thermodynamic aspects of the adsorption process were also scrutinized. The kinetic studies proved that pseudo-second order model is compatible with the experimental data and thermodynamic results revealed that the adsorption process is of endothermic nature. Overall, ultrasonic-assisted preparation of activated carbon from palm shell actuated using Oleic acid was found to be a highly efficient adsorbent which was suitable for acenaphthene removal from aqueous solution.

Identification of Promising RILs for High Grain Zinc Through Genotype × Environment Analysis and Stable Grain Zinc QTL Using SSRs and SNPs in Rice (Oryza sativa L.).

Polished rice is one of the commonly consumed staple foods across the world. However, it contains limited nutrients especially iron (Fe) and zinc (Zn). To identify promising recombinant inbred lines (RILs) for grain Zn and single plant yield, 190 RILs developed from PR116 and Ranbir Basmati were evaluated in two environments (E1 and E2). A subset of 44 contrasting RILs for grain Zn was screened in another two environments (E3 and E4). Phenotypic data was collected for 10 traits, viz., days to 50% flowering, plant height, panicle length, number of tillers, single plant yield (SPY), test weight, Fe and Zn in brown (IBR, ZBR), and polished rice (IPR, ZPR). Stepwise regression analysis of trait data in 190 RILs and a subset of 44 RILs revealed the interdependence of ZPR, ZBR, IPR, and IBR and the negative association of grain Zn with single plant yield. Based on the additive main effect and multiplicative interaction (AMMI) and genotype and genotype × environment interaction (GGE) analyses of the subset of 44 RILs across four environments (E1-E4), six promising RILs were identified for ZPR with >28 ppm. Mapping of 190 RILs with 102 simple sequence repeats (SSRs) resulted in 13 QTLs for best linear unbiased estimates (BLUEs) of traits including advantage over check (AOC). Using genotype-based sequencing (GBS), the subset of 44 RILs was mapped with 1035 single-nucleotide polymorphisms (SNPs) and 21 QTLs were identified. More than 100 epistatic interactions were observed. A major QTL qZPR.1.1 (PV 37.84%) and another QTL qZPR.11.1 (PV 15.47%) were identified for grain Zn in polished rice. A common major QTL (qZBR.2.1 and qZPR.2.1) was also identified on chromosome 2 for grain Zn content across SSR and SNP maps. Two potential candidate genes related to transporters were identified based on network analyses in the genomic regions of QTL < 3 Mb. The RILs identified for grain Zn and SPY were nominated for national evaluation as under rice biofortification, and two QTLs identified based on BLUEs could be used in the rice biofortification breeding programs.